Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1985-03-22
1985-12-24
Michl, Paul R.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
526232, 526342, C08F 436
Patent
active
045607354
ABSTRACT:
A process for preparing .alpha.-methylstyrene/acrylonitrile copolymer by suspension or bulk polymerization of .alpha.-methylstyrene and acrylonitrile with at least one member selected from the group consisting of styrene, chlorostyrene, para-methylstyrene, t-butylstyrene, acrylic ester and methacrylic ester in the presence of a difunctional organic peroxide having a 10 hour half-life temperature of 60.degree. to 120.degree. C. and capable of producing a t-butyl radical, at a polymerization temperature of 80.degree. to 135.degree. C. The process produces the copolymers having excellent transparency, heat resistance and strength in a high conversion in a short time.
REFERENCES:
patent: 3341507 (1967-09-01), Guillet
patent: 3491071 (1970-01-01), Lanzo
patent: 4049605 (1977-09-01), Kobashi
patent: 4169195 (1979-09-01), Rinehart
patent: 4200593 (1980-04-01), van der Loos
patent: 4340723 (1982-07-01), Duyzings
Mori Kiyoshi
Nakagawa Masao
Sugita Toshiaki
Kanegafuchi Kagaku Kogyo & Kabushiki Kaisha
Michl Paul R.
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