Production of oxygenated compounds

Details Production of oxygenated compounds Production of oxygenated compounds

1980-04-22

1984-12-11

Helfin, Bernard

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568429, 568454, 568455, 568311, 568342, 568387, 568715, 568909, 568821, 568826, 562459, 562508, 562577, 562 69, 260465R, 2604651, 564305, 564502, 208 16, C07C 4550, C07C 2916

Patent

active

044879725

ABSTRACT:
This specification discloses a process for the production of oxygenated compounds, more specifically aldehydes and alcohols, by reacting an olefin with hydrogen and carbon monoxide in the presence of, as a ctalyst, an insoluble polymer containing a functional group, which may be an amine, thiol, phosphine, or arsine group, having chemically bonded thereto a metal of Group VIII of the Periodic Table. The metal can be, for example, rhodium, cobalt, or ruthenium. The olefin can contain more than one carbon-to-carbon double bond, may be an open chain or a cyclic olefin, and may be substituted. Further, the olefin may be contained in a refinery stream such as a cracked gasoline. The reaction may be carried out in the presence of a polar solvent.

REFERENCES:
patent: 3636159 (1972-01-01), Solomon
patent: 3824221 (1974-07-01), Ragg
patent: 3825601 (1974-07-01), Rennick
patent: 3847997 (1974-11-01), Allen
patent: 3998887 (1976-12-01), Allen

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