Method for synthesizing 2-ketoaldonic acids

Details Method for synthesizing 2-ketoaldonic acids Method for synthesizing 2-ketoaldonic acids

1995-06-07

1998-06-02

Knode, Marian C.

Chemistry: molecular biology and microbiology

Micro-organism, tissue cell culture or enzyme using process...

Preparing oxygen-containing organic compound

435105, 435232, 536 111, 536 186, 536124, C12P 740, C12P 1902, C12N 988, C07H 100

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active

057598258

ABSTRACT:
2-Ketoaldonic acid is synthesized by aldolase condensation reaction involving pyruvate and an aldose acceptor in the presence of excess pyruvate. After the reaction is substantially complete, the excess pyruvate is removed from the reaction mixture by treatment with pyruvate decarboxylase.

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Liu et. al. J. Am. Chem. Soc. 1992, 114, 3901-3910.
Kim et. al. J. Am. Chem. Soc. 1988, 110, 6481-6486.
Whitesides et. al. Angew. Chemie. 1985, 24, 617-718.
Toone et. al. Tetrahedron 1989, 45, 5365-5422.

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