Method for manufacturing a positive electrode active material fo

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

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429223, H01M 204

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057597170

ABSTRACT:
A method for manufacturing positive a electrode active material for a lithium battery represented by general formula Li.sub.x Mn.sub.2-y M.sub.y O.sub.4 (M: a 2-valency metal, 0.45.ltoreq.y.ltoreq.0.60, 1.ltoreq.x.ltoreq.2.1) having cubic spinel structure of and a lattice constant within 8.190 angstroms by employing a solid phase reaction, comprising the steps of firing a lithium compound, a manganese compound and a metal M compound and refiring the fired material after pressurizing it at least once to remove a metal M oxide.

REFERENCES:
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Mat. Res. Bull., vol. 18 (1983), pp. 461-472. Lithium Insertion Into Manganese Spinels, M.M. Tackeray, W.I.F. David, P.G. Bruce, and J.B. Goodenough (month n/a).
Solid State Ionic 69 (1994), pp. 59-67. Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells, R.J. Gummow, A. de Kock, M.M. Thackeray (month n/a).
Journal of Power Sources, 43-44 (1993), pp. 223-231. The SWING system, a nonaqueous rechargeable carbon metal oxide cell, R. Bittihn, R. Herr and D. Hoge (month n/a).
Journal of Power Sources 52 (1994), pp. 185-192. Determination of thermodynamic, kinetic and interfacial properties for the Li/Li.sub.x Mn.sub.2 O.sub.4 system by electrochemical techniques, J. Barker, R. Pynenburg, R. Koksbang (month n/a).
J. Electrochem. Soc., vol. 183, No. 10 (Oct. 1991), pp. 2859-2864. The Spinel Phase of LiMn.sub.2 O.sub.4 as a Cathode in Secondary Lithium Cells, J.M. Tarascon, E. Wang, and F.K. Shokoohi.
Japanese Patent Application Laid-Open No. 3-285262, filed Dec. 16, 1991.
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Japanese Patent Application Laid-Open No. 4-87268, filed Mar. 19, 1992.
The Spinal Phase of LiMn.sub.2 O.sub.4 as a Cathode in Secondary Lithium Cells by Tarascon.
The Spinal Phases LiMyMn2-yO4 (M=Co, Cr, Ni) as the cathode for rechargeable lithium batteries by Li Guahua et al. Oct. 1991.

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