Method for regenerating phosphorus-molybdenum-alkali containing

Catalyst – solid sorbent – or support therefor: product or process – Regenerating or rehabilitating catalyst or sorbent – Treating with a liquid or treating in a liquid phase,...

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502 24, 502211, 562535, B01J 3866, B01J 2728, B01J 2719, C07C 51235

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active

047074604

ABSTRACT:
A method for regenerating a spent oxidation catalyst useful in the production of unsaturated carboxylic acids by vapor-phase oxidation of unsaturated aldehydes, the catalyst containing, at least, phosphorus, molybdenum, and an alkali metal(s), which method comprises dissolving and/or suspending the spent catalyst in a liquid composition, wherein the contents of ammonium ion and nitrate ion are controlled to be from 7 to 15 moles and from 0.1 to 4.0 moles, respectively, per 12 gram atoms of molybdenum, and immediately thereafter mixing the spent catalyst and the liquid composition.

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patent: 4165296 (1979-08-01), Ishii et al.
patent: 4303550 (1981-12-01), Callahan
patent: 4377501 (1983-03-01), Khoobiar
patent: 4410450 (1983-10-01), Sasaki et al.

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