Method of preparing derivatized polystyrene for spectroscopic st

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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435180, 436531, 525343, 5253593, 525375, 525376, 525378, 525384, C08F 834, C08F 824

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049787241

ABSTRACT:
Molded articles formed of polystyrene or other polymers containing an aromatic moiety can be derivatized on the surface of the article by subjecting the molded article to a chemical reaction wherein the reaction media utilizes tetramethylsulfone as the reactant solvent and a suitable substituent group which is substituted on to the aromatic moiety of the polystyrene or other polymer by electrophilic substitution. By choosing the substituent group to further include a leaving group, further substitution of the primary substituent can be effected normally by nucleophilic substitution reaction. In this way, biologically important molecules can be attached to a polystyrene or other aromatic containing polymer without effecting certain properties of the molded article such as its optical or spectroscopic clarity.

REFERENCES:
patent: 2404722 (1946-07-01), Houtz
patent: 2460579 (1949-02-01), Houtz
patent: 4031038 (1977-06-01), Grinstead
patent: 4087599 (1978-05-01), Roe
patent: 4089815 (1978-05-01), Reiter
patent: 4315998 (1982-02-01), Necker5s

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