Preparation of dl-.alpha.-tocopherol

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07D31172

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042527260

ABSTRACT:
dl-.alpha.-Tocopherol is prepared by condensing trimethylhydroquinone with phytyl halide in a chlorinated lower aliphatic hydrocarbon solvent, in the presence of metallic tin and a Friedel-Crafts catalyst.

REFERENCES:
patent: 3455959 (1969-07-01), Mayer et al.
patent: 3651113 (1972-03-01), Metlesics et al.
patent: 3789086 (1974-01-01), Frick et al.
Eisai, Derwent No. 65663Y, 1-28-76.

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