Porphocyanine and CNC-expanded porphyrins

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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540472, 514185, 534 14, 534 15, C07D48722

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active

057263043

ABSTRACT:
Compounds of the formula ##STR1## and the metalated forms and salts thereof; wherein n is an integer of 1-4; and

REFERENCES:
Barnett et al., "Pyrrole chemistry XII. Synthetic Approaches to Cyanopyrroles", Can J. Chem., 58, 409-411 (1979).
Demopolulos et al., "Pyrrole Chemistry. XXVI. A Synthesis of Porphobilinogen from Pyrrole", Can. J. Chem., 61, 2415-76 (1983).
Loader et al.. "Pyrrole Chemistry. XXIII. The Cyanation of Substituted Pyrroles with Chlorosulfonyl Isocyanate (CSI). New Syntheses of Pyrrole-3-carbonitriles", Can. J. Chem., 2673-76 (1981).
Dhar et al., "Recent Advances in the Chemistry of Chlorosulfonyl Isocyanate", Synthesis, 437-49 (1986).
Floyd et al., "Direct Cyanation of the Furan Nucleus by Chlorosulphonyl Isocyanate", Tetrahedron, 39, 3881-85 (1983) and.
Vorbruggen, "Reaktive Isocyanate I. Die Direkte Einfuehrung von Nitril-Gruppen in Ungesattigte System. Eine Einfache Umwandlung von Carbonsauren in Ihre Nitrile", Tetrahedron Letters, 13, 1631-34 (1968).
Vonbruggen et al., "The Introduction of Nitrile-Groups into Heterocycles and Conversion of Carboxylic Groups into their Corresponding Nitriles with Chlorosulfonylisocyanate and Triethylamine", Tetrahedron, 50:22, 6549-58 (1994).

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