Hydrocarbon conversion by catalytic distillation

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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203DIG6, 568694, 585709, 585446, C07C 4106

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active

053959817

ABSTRACT:
Ethers suitable for use as high octane oxygenate additives for motor fuels or other compounds such as alcohols or alkylates are produced in a catalytic distillation process wherein a C.sub.4 -plus isoolefin(s) and an alcohol present in the catalytic distillation zone overhead stream are charged to a packed liquid-phase reaction zone containing an etherification catalyst before being recycled to the overall catalytic distillation zone. The effluent of the liquid-phase reactor is returned to the catalytic distillation zone at a point above the catalyst in this zone. The feed(s) to the process passes directly into the catalytic distillation zone, without passage through a prereactor, at a point located below a majority of catalyst bed in the catalytic distillation zone.

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patent: 4307254 (1981-12-01), Smith, Jr.
patent: 4950803 (1990-08-01), Smith, Jr. et al.
patent: 5118871 (1992-06-01), Cikut et al.
patent: 5258560 (1993-11-01), Marker

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