Tetra(neophyl) zirconium and its use in process for the polymeri

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526156, 526160, 526170, C08F 206, C08F 464, C08F 1002, C08F 1006

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active

040113833

ABSTRACT:
There are disclosed olefin polymerization catalysts based on tetra(neophyl) zirconium and its reaction products with surface-hydroxylated oxides of metals of Groups II(a), III(a), IV(a) and IV(b) of the Periodic Table of the Elements, processes for their preparation, and processes for the polymerization of olefinic monomers employing such catalysts. Neophyl zirconium aluminate supported on alumina is disclosed as the preferred, most active catalyst. The polyolefins produced are linear high polymers of high crystallinity such as polyethylene and isotactic polypropylene. Diolefins are converted into rubber by use of the process employing the catalyst. Ethylene-propylene copolymer rubbers can also be produced by use of the catalysts.

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patent: 3712874 (1973-01-01), Kruse
patent: 3840508 (1974-10-01), Ballard et al.
patent: 3840511 (1974-10-01), Ballard et al.
patent: 3875132 (1975-04-01), Kruse
patent: 3932307 (1976-01-01), Setterquist

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