Process for producing alcohols by hydrogenolysis of carboxylic a

Details Process for producing alcohols by hydrogenolysis of carboxylic a Process for producing alcohols by hydrogenolysis of carboxylic a

1985-08-08

1986-12-09

Evans, J. E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

502242, 502259, 502301, 502326, 568799, 568814, 568864, C07C 29136, C07C 37055

Patent

active

046281304

ABSTRACT:
The invention has as an object the production of alcohols by hydrogenolysis of carboxylic acid esters, under hydrogen pressure, in the presence of a catalyst resulting from the incorporation of at least one compound of at least one metal from the group consisting of germanium, tin and lead to Raney nickel or to a nickel-containing carrier. The reaction is preferably conducted at a temperature from 180.degree. to 330.degree. C. and under a pressure from 1 to 10 MPa.

REFERENCES:
patent: 2093159 (1937-09-01), Schmidt
patent: 2322095 (1943-06-01), Schmidt
patent: 3829448 (1974-08-01), Kanetaka et al.
patent: 4224248 (1980-09-01), Birdenstock et al.
patent: 4456775 (1984-06-01), Travers et al.
R. Montarnal et al, "Coordination in Applied Heterogeneous Catalysts", May-Jun. 1977, vol. XXXII, No. 3, pp. 370, 371, 384.

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