Process for the production of dihydroxybenzenes

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568741, 568803, C07C 3700

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active

046281266

ABSTRACT:
The nuclear hydroxylation of phenol with organic solutions of hydrogen peroxide in the presence of a catalyst is carried out in improved manner by employing both (1) a special, practically water free solution of hydrogen peroxide in an organic solvent which does not form an azeotrope with water or whose highest azeotrope with water, boil near or above the boiling point of hydrogen peroxide, and (2) employing as a catalyst XO.sub.2 where X is sulfur, selenium, or tellurium. Besides increasing the yield and the ability to carry out the reaction in a simpler manner when selenium dioxide is employed as a catalyst, there can also be controlled the ortho-para ratio, respectively, the ortho-ortho ratio of the product.

REFERENCES:
patent: 3943179 (1976-03-01), Bost
Ullmanns Encyklopadie der Technischen Chemie 4., Neubearbeitete und Erweiterte Auflage-Band 17-Milchsaure bis Petrolkoks.

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