Biologically active compounds by catalytic olefin metathesis

Details Biologically active compounds by catalytic olefin metathesis Biologically active compounds by catalytic olefin metathesis

1997-05-27

1999-06-29

Kight, John

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

526171, 556136, 568886, C08F 472, C08F 480, C07F 1400, C07C 2912

Patent

active

059169834

ABSTRACT:
Biologically active compounds such as pheromones and precursors thereof are produced by catalyzed cross metathesis of dissimilar terminal olefins or of a cyclodiene and a terminal olefin.

REFERENCES:
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patent: 5342909 (1994-08-01), Grubbs et al.
Nguyen et al., "Ring-Opening Metathesis Polymerization (ROMP) of Norbornene by Group VIII Carbene Complex in Protic Media," 114 J.A.C.S. 3974 (1992).
Nguyen et al., "Syntheses and Activities of New Single-Component, Ruthenium-Based Olefin Metathesis Catalysts," 115 J.A.C.S. 9858 (1993).
Randall et al., "Selective Ring-Opening Cross-Metathesis. Short Syntheses of Multifidene and Viridiene," J.A.C.S. 9610 (1995).
Schwab et al., "Synthesis and Applications of RuCl.sub.2 (.dbd.CHR')(PR.sub.3).sub.2 : The Influence of the Alkylidene Moiety on Metathesis Activity," 118 J.A.C.S. 100 (1996).
Schneider et al., "Selective Ring-Opening Olefin Metathesis of Funtionalized Monosubstituted Olefins," 36 Angew. Chem. Int. Ed. Engl. 257 (1997).

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