Fluorinated diazabicycloalkane derivatives

Organic compounds -- part of the class 532-570 series – Organic compounds – Unsubstituted hydrocarbyl chain between the ring and the -c-...

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544351, 540556, 540465, 540541, C07D48708, C07D24504

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active

054730651

ABSTRACT:
The present invention relates to novel N,N'-difluorinated diazabicycloalkane derivatives which are useful as electrophilic fluorinating agents, processes for preparing such N,N'-difluorinated diazabicycloalkane derivatives and methods of using such compounds as fluorinating agents. The invention also presents novel N-fluorinated azaazoniabicycloalkane-Lewis acid adduct intermediates which are formed in the processes for preparing such N,N'-difluorinated diazabicycloalkane derivatives.

REFERENCES:
patent: 4935519 (1990-06-01), Van Der Puy et al.
patent: 5086178 (1992-02-01), Banks
J. M. Van Paasschen et al. (Can. J. Chem. 1975, 53, 723-726).
J. M. Van Paasschen et al. (J. Inorg. Nucl. Chem. 1976, 38, 2322-2323).
T. Umemoto et al. (Bull. Chem. Soc. Jpn. 1991, 64, 1081-1092).
R. E. Banks et al., J. Chem. Soc., Chem. Commun. 1992, 595-596).

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