Elimination of film defects due to hydrogen evolution during cat

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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2041806, 2041816, C25D 1310

Patent

active

050663747

ABSTRACT:
This invention is directed to a method for eliminating or reducing pinhole defects in cataphoretically deposited films without interfering with the electrolysis of water needed for electrodeposition. This method comprises decreasing the evolution of hydrogen gas at the cathode by adding a compound to the emulsion. This compound is reduced by the hydrogen produced at the cathode during the electrodeposition. The hydrogen reacts with the this non-gaseous compound rather than becoming hydrogen gas and forming bubbles which lead to pinhole defects.

REFERENCES:
patent: 4108817 (1978-08-01), Lochel
patent: 4592816 (1986-06-01), Emmons et al.
patent: 4877818 (1989-10-01), Emmons et al.

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