Polysiloxane graft copolymers, flexible coating compositions com

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

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525474, 525476, 525477, 525479, 528 26, 528 27, 528 32, 528 33, 528 41, C08G 7704

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048047325

ABSTRACT:
A thermosetting coating composition adapted to form a flexible cured coating over a variety of substrates, such as metal and plastic containing a hydroxy functional urethane modified polysiloxane graft copolymer and an alkylated melamine crosslinking agent. The copolymer has a number average molecular weight between about 1,000 and about 4,000, has a hydroxyl number between about 30 and about 300, contains about 1-10 urethane linkages per molecule and is the reaction product of carbon-carbon double bond-reactive monoethylenically unsaturated monomer with hydroxy functional carbon-carbon double bond-bearing branched polysiloxane macromer. The macromer is the reaction product of glycidyl methacrylate and hydroxy functional polysiloxane reactant containing 1-10 urethane linkages per molecule.

REFERENCES:
patent: 4208471 (1980-06-01), Bresak et al.
patent: 4673718 (1987-06-01), Ryntz et al.

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