Palladium catalyst systems for selective hydrogenation of dienes

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 24, C07F 900

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active

054751217

ABSTRACT:
A catalyst precursor is provided that is useful in the selective hydrogenation of olefinic unsaturation in polymers or copolymers. The precursor comprises a palladium salt that is complexed with a complexing agent selected from the group consisting of organic phosphates, dialkylidene acetones, and tetraalkyl ammonium hydroxides. The catalyst precursor may be used in batch, step-wise addition, or continuous systems.

REFERENCES:
patent: 3678085 (1972-07-01), Rick et al.
patent: 4190595 (1980-02-01), Diamond et al.
patent: 4645849 (1987-02-01), Lewis

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