Second-order nonlinear optical polymer and method for producing

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525279, 525293, 525291, 5253282, 525376, 525377, 526298, 526311, 526257, 528372, C08F22230, C08F22806, C08F 832

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active

053590082

ABSTRACT:
The present invention provides a second-order nonlinear optical polymer including a polymer backbone and side groups bonded to the polymer backbone, wherein the side groups include one or more of a first nonlinear optical group represented by the following formula (C-1) and one or more of a second nonlinear optical group represented by the following formula (C-2) or (C-2)': ##STR1## wherein .pi..sub.1 to .pi..sub.n, .pi.'.sub.1, .pi.'.sub.2, and .pi.".sub.1 each represent independently a .pi.-conjugated cyclic compound group; X.sub.1 to X.sub.n-1, X'.sub.1, Y.sub.1 to Y.sub.n-1, and Y'.sub.1 each represent independently CH, N, or N.fwdarw.O; A.sub.1, A.sub.2, and A.sub.3 each represent independently an electron attracting group; D.sub.1, D.sub.2, and D.sub.3 each represent independently an electron donating group; and n represents an integer of 3 or greater.

REFERENCES:
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Engle, M. et al. (1985) Pure & Appl. Chem. 57(7), 1009-1014.
"Electro-optic phase modulation and optical second-harmonic generation in corona-poled polymer films", Singer et al., Appl. Phys. Lett., vol. 53, No. 19, pp. 1800-1802, Nov. 7, 1988.
"Developments of Optically Nonlinear Polymers and Devices", Moehlmann, G., Synthetic Metals, vol. 37, pp. 207-221, 1990.
"Optical nonlinearities of conjugated molecules. Stilbene derivatives and highly polar aromatic compounds", Oudar, J. L., The Journal of Chemical Physics, vol. 67, No. 2, pp. 446-457, Jul. 15, 1977.
"Second-order nonlinearity of a novel diazo-dye-attached polymer", Amano et al., J. Appl. Phys., vol. 68, No. 12, pp. 6024-6028, Dec. 15, 1990.

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