Process for preparing difluorochloromethoxybenzenes

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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560 18, 560 59, 560 65, 558423, 558424, 568 44, 568 49, 568 53, 568637, 568642, 568643, 568655, 568656, 568586, C07C 43225, C07C 4100

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049142445

ABSTRACT:
Difluorochloromethoxybenzenes are prepared by reacting phenols with trichloromethyl chloroformate (=di-phosgene) in the presence of hydrogen fluoride.

REFERENCES:
patent: 3213062 (1965-10-01), Ellingboe
Weygard, Preparation Organic Chemistry, John Wiley & Sons, N.Y., 1972, pp. 378-379.
Ramsperger et al., J. Amer. Chem. Soc., vol. 55, pp. 214-217, Jan. 1933.
Houben--Weyl "Methoden der Organischen Chemie, Band E4: Kohlensaure-Derivative", 4th Edition, 1983, Georg Thieme Verlag, Stuttgart--New York Seiten 626-628, 1204.

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