Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing
Patent
1991-04-04
1992-09-08
Brust, Joseph Paul
Organic compounds -- part of the class 532-570 series
Organic compounds
Amino nitrogen containing
548418, C07C21145, C07C21156
Patent
active
051459990
ABSTRACT:
1-[2,2-bis(trifluoromethyl)-3,3,4,4,5,5,5-heptafluoropentyl]-3,5-diaminoben zene and 1-[2,2-bis(trifluoromethyl)-3,3,4,4,5,5,5-heptafluoropentyl]-4-aminobenzen e, as well as fluorinated polymers, preferably polyimides. The perfluoroalkyl group of these amines is connected to the benzene ring through a tertiary carbon atom followed by a methylene group. This renders the amines more reactive than other amines, where the perfluoroalkyl group is connected directly to the benzene ring. The absence of hydrogen from the group containing the tertiary carbon atom which is adjacent to the perfluorinated groups, prohibits dehydrofluorination.
REFERENCES:
C.A. 109:149040q, (1988), Nakayama, et al.
C.A. 108:94127v, (1980), Ikeda, et al.
Auman Brian C.
Higley David P.
Scherer Kirby V.
Brust Joseph Paul
E. I. Du Pont de Nemours and Company
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