Production of particulate amide/imide prepolymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528125, 528126, 528128, 528170, 528172, 528173, 528176, 528183, 528188, 528220, 528229, 528310, 528312, 528332, 528350, 528351, 525282, 525436, C08G 7314, C08G 6928, C08L 7710, C08L 7908

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051459434

ABSTRACT:
Fusible polyimide powders are prepared by the process of this invention. An amic acid amine is first prepared by treating (n+1) moles of a bis(aminophenyl)methane with n mole of aromatic tetracarboxylic anhdride to produce an aromatic amic acid prepolymer. This prepolymer is then mixed with an unsaturated carbocyclic monoanhydride and the mixture heated to form a reactive end-capped polyamic acid precursor. The resulting composition is thermally treated in order to partially imidize the precursor. The resulting fusible polyimide powder is finally separated.

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CA 113: 79900b, "Imide Oligomer Comp. for heat-resistant Polyimides".

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