Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1981-01-07
1982-09-07
Warren, Charles F.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260155, 260156, 260157, 260158, 260165, 260205, 260206, 260207, 2602071, 2602075, C07C10704, C07C10706, C09B 4300
Patent
active
043483194
ABSTRACT:
The invention relates to a process for the preparation of azo dyestuffs containing a cyano group in the ortho-position relative to the azo bridge, by reacting corresponding orthohalogeno-azo dyestuffs with metal cyanides in an aqueous medium in the presence of phase transfer catalysts, such as those from the series of quaternary ammonium and phosphonium salts and also tertiary sulphonium salts.
Compared with known processes for the preparation of o-cyano-azo dyestuffs the new method has the advantage of simpler, cheaper handling, improved yields and lesser pollution problems.
REFERENCES:
patent: 3876621 (1975-04-01), Hagen et al.
patent: 3978040 (1976-08-01), Gottschlich et al.
Ullmanns Encyklopadie der technischen Chemie, Edition II, vol. 16, Urban & Schwarzenberg: Munchen-Berlin, 1965, pp. 724-742.
Ullmanns Encyklopadie der technischen Chemie, Edition II, vol. 9, Urban & Schwarzenberg: Munchen, 1957, pp. 297-304.
Starks, "Journal of the American Chemical Society", vol. 93, 1971, pp. 195-199.
Ullman, vol. 16, pp. 724-726.
Bayer Aktiengesellschaft
Warren Charles F.
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