Production of organolithium compounds and lithium hydride

Details Production of organolithium compounds and lithium hydride Production of organolithium compounds and lithium hydride

1980-03-04

1982-10-19

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

423646, C07F 102

Patent

active

043549829

ABSTRACT:
A catalytic system is provided for the lithiation of .alpha.-olefins and .alpha.,.omega.-diolefins with concurrent production of lithium hydride. The catalysts include oxygen and sulfur containing organic compounds and polycyclic aromatics which can be combined with alkali metals and/or transition metal compounds. High yields of pure and stereospecific lithiated olefins are obtainable.

REFERENCES:
patent: 3848008 (1974-11-01), Fetters
patent: 3903168 (1975-09-01), Foss et al.
patent: 4067917 (1978-01-01), Sigwalt et al.
patent: 4075253 (1978-02-01), Horiie et al.

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