Process for removing sulfur compounds from industrial gases

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

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4232441, 423230, 423572, 4235768, C01B 1700

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active

059852275

ABSTRACT:
A process is provided for removing sulfur compounds, such as carbonyl sulfide, carbon disulfide, mercaptans and hydrogen sulfide out of a gas, such as methane, carbon dioxide, carbon monoxide, nitrogen and methane, by saturating the sulfur compound contaminated gas with steam; hydrolyzing any carbonyl sulfide, carbon disulfide and mercaptans in the gas stream into hydrogen sulfide by contacting the steam and sulfur compound contaminated gas with a catalyst containing an inorganic support uniformly impregnated with a mixture of at least one oxide selected from Group VI transition metals and at least two oxides selected from Groups I, II, VI and VIII transition metals at a temperature of about 20.degree. C. to about 150.degree. C.; oxidizing the hydrogen sulfide in the gas exiting the previous hydrolysis step by contacting the hydrogen sulfide containing gas together with at least a stoichiometric quantity of air and/or oxygen with the catalyst at a temperature of about 15.degree. C. to about 50.degree. C. to produce a sulfur loaded catalyst and a desulfurized gas. The sulfur loaded catalyst may be regenerated with steam.

REFERENCES:
patent: 3518208 (1970-06-01), Schneider
patent: 3536755 (1970-10-01), Parthasarathy et al.
patent: 3554689 (1971-01-01), Bloembergen etal.
patent: 4332781 (1982-06-01), Lieder et al.
patent: 4629612 (1986-12-01), van der Wal et al.

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