Catalysts, method of preparing these catalysts, and polymerizati

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526117, 526120, 526126, 526131, 526134, 526352, 5263486, C08F 416, C08F 1000

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054830141

ABSTRACT:
A polymerization process for olefins, diolefins and/or acetylenically unsaturated monomers is described. The monomers are contacted with an ionic catalyst which comprises a cyclopentadienyl derivative of Group IV-B metals as cation and a compatible non-coordinating anion containing a plurality of boron atoms. Borate, carborate, borane, carborane, metallaborane and metallacarborane compounds exemplify anion sources and dihydrocarbyl-substituted bis(cyclopentadienyl) zirconium compounds exemplify the Group IV-B metal cation sources.

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