Catalyst to dehydrogenate paraffin hydrocarbons

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And group viii containing

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B01J 2100

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active

057364788

ABSTRACT:
A new catalyst for the selective conversion of isobutane to isobutylene. This catalyst also could be applied to the selective dehydrogenation of other light paraffins such as propane and n-butane. The catalyst is comprised of platinum, tin, and potassium supported on K--L-zeolite. This catalyst exhibits greater than 98% selectivity for conversion of isobutane to isobutylene at isobutane conversion levels greater than 50%. In addition, this catalyst exhibits excellent stability. The preferred catalyst would have an atomic ratio of Sn to Pt greater than 1.0 as well as an atomic ratio of K to Pt greater than 1.0.

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Pujado et al, Production of LPG Olefins by Catalytic Dehydrogenation, vol. 4, No. 3, pp. 186-191, Energy Progress, Sep., 1984.
Atkins et al, Catalytic Dehydrogenation: A Review of Current Processes and Innovations, pp. 201-210, DGMK-Conference, Selective Hydrogenation and Dehydrogenation, on Nov. 11-12, 1993 in Kassel/Germany.

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