Process for the preparation of 2,5-dihydrofuran

Details Process for the preparation of 2,5-dihydrofuran Process for the preparation of 2,5-dihydrofuran

1979-10-12

1981-03-10

Raymond, Richard

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

568857, 568861, C07D30728

Patent

active

042553385

ABSTRACT:
A process for the hydrogenation of butadienepolyperoxide in a suitable solvent, e.g., tetrahydrofuran, at temperatures of 75.degree.-110.degree. C. and pressure above 2000 psia by contacting the butadienepolyperoxide and hydrogen in the presence of metallic silver. The process produces 1-butene-3,4-diol and 2-butene-1,4-diol.

REFERENCES:
patent: 2440678 (1948-05-01), Ford et al.
patent: 2879306 (1959-03-01), Hutchinson
patent: 4002692 (1977-01-01), Mabuchi et al.
patent: 4112004 (1978-09-01), Mabuchi et al.
patent: 4123616 (1978-10-01), Mabuchi et al.
Handy et al., J.A.C.S., vol. 80 (1958) pp. 5306-5308.

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