Titanium chelate catalyst

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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502150, C07F 728

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active

045072469

ABSTRACT:
Poly(alkylene dicarboxylates) such as poly(alkylene terephthalates) are prepared by reacting a dicarboxylic acid or alkyl ester thereof with an alkanediol in the presence of a titanium-containing chelate compound which may be prepared by the reaction of a tetraalkyl titanate with an ortho-disubstituted hydroxyaromatic compound of the formula ##STR1## wherein X.sup.1 is hydrogen, lower alkyl or lower aryl. Polymerization by this method minimizes ester-carbonate interchange in blends of the poly(alkylene dicarboxylates) with aromatic polycarbonates. The chelates in which X.sup.1 is lower alkyl or lower aryl are novel compounds.

REFERENCES:
patent: 2926184 (1960-02-01), Irish et al.
patent: 3006941 (1961-10-01), Mudrak et al.
patent: 4339503 (1982-07-01), Rukavina
Chemical Abstracts, 92, 58911p, (1980).

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