Manufacture of butanedicarboxylic acid esters

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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502 20, 502 28, 502152, 502155, 502326, 560190, 560207, C07C 6738

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active

046187022

ABSTRACT:
Increased catalyst concentration relative to butadiene in its carboalkoxylation permits operation at reduced pressure and simplifies process steps.

REFERENCES:
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patent: 4169956 (1979-10-01), Kummer et al.
patent: 4171451 (1979-10-01), Kummer et al.
patent: 4258203 (1981-03-01), Platz et al.
patent: 4259520 (1981-03-01), Kummer et al.
patent: 4310686 (1982-01-01), Kummer et al.
The Cobalt Carbonyl-Catalyzed Hydroesterification of Butadiene with Carbon Monoxide and Methanol, Akio Matsuda, Bulletin of the Chemical Society of Japan, vol. 46, 524-430 (1973).
Mechanistic Pathways in the Catalysis of Olefin Hydrocarboxylation by Rhodium, Iridium, and Cobalt Complexes, D. Forster et al., Catal. Rev.-Sci. Eng., 23(1&2) pp. 89-105 (1981).
Imyanitov et al., Karbonilirovanie Menasyshchennykh Uglevodorodov (1968) 225-32, 232-43, CA 71, 21648y-21649z (1969).

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