Conversion of dienes or monoolefins to diesters

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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252439, 2604106, 260464, 260465D, 2604654, 560 1, 560 60, 560 83, 560 84, 560 85, 560 87, 560 89, 560105, 560106, 560111, 560112, 560122, 560125, 560127, 560192, 560193, 560197, 560199, 560228, 560229, 560230, C07C 6705

Patent

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041623630

ABSTRACT:
Conjugated dienes or monoolefins are converted to diesters in a process utilizing a catalyst system comprising an alkali metal compound and a sulfur source comprising elemental sulfur or a sulfur halide, optionally with a halide source, in carboxylic acid media.

REFERENCES:
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patent: 2903480 (1959-09-01), Toland
patent: 2985521 (1961-05-01), Herman
patent: 3119874 (1964-01-01), Paszthory
patent: 3119875 (1964-01-01), Steinmetz
patent: 3634496 (1972-01-01), Kominami
patent: 4026924 (1977-05-01), Stapp
Suzuki, Ind. and Eng. Chem. Prod. Res. Dev., 10, pp. 179-183 (1973).
Hill, Chem. Rev., 61, pp. 537-562 (1961).

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