Process for producing two-carbon atom compounds from synthesis g

Details Process for producing two-carbon atom compounds from synthesis g Process for producing two-carbon atom compounds from synthesis g

1977-10-11

1979-07-24

Mars, Howard T.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2604496R, 2604495, 252454, 252460, 252459, 252458, C07C 2706

Patent

active

041622626

ABSTRACT:
A process for selectively preparing a mixture of two-carbon atom oxygenated hydrocarbons while minimizing the co-production of methanol which comprises continuously contacting a gaseous reaction mixture containing hydrogen and carbon monoxide with a solid catalyst comprising rhodium in combination with thorium and/or uranium at reaction conditions correlated so as to favor the formation of a substantial proportion of such two-carbon atom products.

REFERENCES:
patent: 2553398 (1951-05-01), Atwell
patent: 2583611 (1952-01-01), Sullivan
patent: 2616914 (1952-11-01), Riblett
patent: 3833634 (1974-09-01), Pruett et al.
Eidus et al., Translated from Izvestiya Akad Nauk SSSR, Seriya Khim, No. 7 (pp. 1160-1169) Jul. 1965, pp. 1129-1135.
Kratel, Doctoral Dissertation, Technical University of Berlin-Charlottenburg 1937, pp. 62-72 done at Kaiser Wilhelm Instit. Mulheim-Ruhr.
Pichler, Brennstoff-Chemie 19, 226-230, 1938.

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