Novel product and process

Details Novel product and process Novel product and process

1986-09-22

1987-10-27

Foelak, Morton

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

From reactant having at least one -n=c=x group as well as...

521128, 521129, 521902, 528 44, 528 53, C08G 1808

Patent

active

047030992

ABSTRACT:
Disclosed are novel compositions capable of catalytically trimerizing organic isocyanates said compositions comprising solutions of the reaction products obtained by reacting in an inert solvent in substantially equimolar proportions electron-rich ketene-aminals with electron-poor olefins having the respective formulae (I) and (II) ##STR1## The variously substituted electron-rich ketene-aminals (I), as the name implies, have high electron density associated with the double bond because of the two tertiary amine groups while the electron-poor olefins (II) have the opposite situation due to the presence of electron withdrawing substituents R.sub.9 and R.sub.10.
Also disclosed is an improved process for trimerizing organic isocyanates using the above catalyst compositions including the preparation of polyisocyanurate polymers and isocyanurate-modified polyisocyanates.

REFERENCES:
patent: 3330828 (1967-07-01), Grogler et al.
patent: 4111914 (1978-09-01), Kresta et al.
patent: 4536490 (1985-08-01), Regelman
patent: 4632989 (1986-12-01), Regelman
Gompper et al., Angewandte Chemie, Int. Ed., 6, 453 (1967).

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