Pesticidal tris-oximino heterocyclic compounds

Details Pesticidal tris-oximino heterocyclic compounds Pesticidal tris-oximino heterocyclic compounds

1997-12-22

2000-11-21

Gerstl, Robert

Drug, bio-affecting and body treating compositions

Designated organic active ingredient containing

Having -c-, wherein x is chalcogen, bonded directly to...

5142292, 544 65, 548131, 548143, 562868, 564157, 564164, C07D27106

Patent

active

06150386&

DESCRIPTION:

BRIEF SUMMARY
The invention relates to novel pesticidally active compounds of the formula I ##STR2## and their possible isomers and isomer mixtures, in which ##STR3## and in which the other substituents are defined as follows: A alkanediyl which is unsubstituted or substituted by methyl and has 1 to 3 carbon atoms, preferably dimethylene (ethane-1,2-diyl); cyclopropyl, C.sub.1 -C.sub.4 alkoxymethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio or cyano; cyano, substituted or unsubstituted C.sub.1 -C.sub.6 alkoxycarbonyl, substituted or unsubstituted di-(C.sub.1 -C.sub.6 alkyl)aminocarbonyl, substituted or unsubstituted heteroaryl, substituted or unsubstituted heterocyclyl, naphthyl; ##STR4## D identical or different halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 haloalkoxy, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 alkynyloxy, C.sub.1 -C.sub.4 alkylenedioxy, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.1 -C.sub.4 -alkoximino-C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.8 -alkiminoxy, cyanomethoxy, cyano-C.sub.1 -C.sub.2 alkoxy, cyano, nitro, thioamido, thiocyanatomethyl, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.2 alkoxy, halo-C.sub.1 -C.sub.6 alkylsulfonyl, di-C.sub.1 -C.sub.4 alkylarnino-C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkynyl, substituted or unsubstituted phenyl, substituted or unsubstituted heteroaryl, tri(C.sub.1 -C.sub.4 alkyl)silyl or di(C.sub.1 -C.sub.4 alkyl)phenylsilyl; --S(O).sub.m --, --(C.sub.1 -C.sub.4 alkyl)--S(O).sub.m -- or --S(O).sub.m --(C.sub.1 -C.sub.4 -Alkyl)--; cycloalkyl, C.sub.2 -C.sub.6 alkenyl which is unsubstituted or substituted by 1 to 3 halogen atoms, or C.sub.3 -C.sub.6 alkynyl, or furthermore aryl, heteroaryl or heterocyclyl, all three of which independently of one another are unsubstituted or substituted one to five times by C.sub.1 -C.sub.6 alkyl, halo-C.sub.1 -C.sub.6 alkyl, halogen, C.sub.1 -C.sub.6 alkoxy or halo-C.sub.1 -C.sub.6 alkoxy, tri(C.sub.1 -C.sub.4 alkyl)silyl, di(C.sub.1 -C.sub.4 alkyl)phenylsilyl or a group ##STR5## R.sub.5, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 independently of one another hydrogen, C.sub.1 -C.sub.4 alkyl or halogen and p 0,1,2 or 3; 1 to 5 halogen atoms, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.2 alkyl, C.sub.2 -C.sub.6 alkenyl which is unsubstituted or substituted by 1 to 3 halogen atoms, C.sub.2 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 cycloalkyl which is unsubstituted or substituted by 1 to 4 halogen atoms, C.sub.3 -C.sub.6 cycloalkyl-C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by 1 to 4 halogen atoms, cyano-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxycarbonyl-C.sub.1 -C.sub.2 alkyl, phenyl-C.sub.1 -C.sub.3 alkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, cyano, nitro or C.sub.1 -C.sub.4 alkylenedioxy, where the phenyl group can be substituted one to three times in an identical or different manner; phenyl which is unsubstituted or substituted once or twice, independently of one another, by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.1 -C.sub.2 haloalkyl having 1 to 3 halogen atoms, nitro or cyano; or pyridyl which is unsubstituted or substituted once or twice, independently of one another by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.1 -C.sub.2 haloalkyl having 1 to 3 halogen atoms, nitro or cyano.
The compounds according to the invention have fungicidal, acaricidal and insecticidal properties and are suitable as active compounds for use in agriculture, in horticulture and in the hygiene sector.
The invention furthermore relates to a process for the preparation of the compounds according to the invention, and to fungicidal, acaricidal and insecticidal compositions which comprise such compounds as active compounds, and to the use of such compounds and compositions for the control of phytopathogenic fungi, Acarina and insects and for prevention of such infestation.
If asymmetric carbon atoms are present in the compounds of the formula I, the compounds occur i

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