Organic material for non-linear optics

Optical waveguides – Having particular optical characteristic modifying chemical... – Of waveguide core

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252582, 359326, 385122, 558423, G02F 135

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053217918

ABSTRACT:
An organic material for non-linear optics, in which the structure of the molecule includes an electron donor group and an electron attractor group connected by means of an electron-transmitting group, the material being characterized by the fact that it satisfies the formula: ##STR1## where R is selected from (CH.sub.3).sub.2 N and CH.sub.3 O, with the first material being dimethylamino 4, cyano 4' biphenyl and the second being methoxy 4, cyano 4' biphenyl.

REFERENCES:
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Makarov, et al., C.A., 106 (1987); 106: 179111u.
Ruoliene, et al, C.A., 102 (1983); 102:15553f.
Barnik, et al. "Optical Second Harmonic Generation in Various Liquid Crystalline Phases," Molecular Crystals and Liquid Crystals, vol. 98, No. 1/4, pp. 1-12 (1983).
Williams, David J., "Organic Polymeric and Non-Polymeric Materials with Large Optical Nonlinearities," Angew. Chem. Int. Ed. Engl. 23 (1984), pp. 690-703.
Davydov, B., et al., "New nonlinear organic materials for generation of second harmonic of neodymium laser radiation," Sov. J. Quantum Electron, vol. 7, No. 1, pp. 129-131.
S. Allen et al. "A CNDOVSB program for the calculation of second-order molecular polarisabilities, and its application" pp. 20-26, Aug. 1986 San Diego, Calif.
G. Berkovic et al. "Second-order nonlinear polarizability of various biphenyl derivatives" pp. 945-949 Jun. 6th, 1987 Optical Soc. of America US.
E. I. Negishi et al. "Selective carbon-carbon bond formation via transition metal catalysis. 3.1.A Highly selective synthesis of unsymmetrical . . ." J. Org. Chem., 42 (1977) pp. 1821-1823.
H. Quast and E. Schmitt, "Ylide durch Decarboxylierung von N-Methyl-carbonsaurebetainen des Pyridins, Chinolins und Isochinolins" pp. 43-63, Jul. 23, 1969.

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