Olefin polymerization process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526127, 526151, 526152, 526279, 5263484, 526905, 502102, 502154, C08F 452

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051090856

ABSTRACT:
A process for polymerizing olefins is disclosed which makes use of a catalyst comprising a cyclopentadienyl lanthanide halide alkali metal ether complex in combination with a cocatalyst comprising an alkali or alkaline earth metal alkyl. Preferred embodiments include the use of hydrogen during the polymerization or the use of an organoaluminum hydride as an additional cocatalyst.

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Inorg. Chem., 20, 3267-3270 (1981), T. Don Tilley and Richard A. Andersen; 3271-3278, Patricia L. Waton, John F. Whitney, and Richard L. Harlow.

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