Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...
Patent
1992-03-04
1994-06-14
Smith, Edward J.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Plural component system comprising a - group i to iv metal...
502113, 502128, 502134, 526116, 526125, 5263486, 526352, C08F 4654, C08F 1000
Patent
active
053209940
ABSTRACT:
The process comprises, in a first step, the reduction of a titanium (IV) compound in an .alpha.,.omega.-dihalogenoalkane using a molar excess of at least one halogenated organoaluminium compound in the absence of an ether, and then in a second step, the addition of a reaction mixture of a compound capable of forming a magnesium halide in-situ, without additional reduction of the titanium compound obtained in the first step. The catalyst contains at least one titanium compound, at least one halogenated organoaluminium compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogenoalkane; the titanium cmpound is essentially a titanium (III) compound, the total titanium (II) and titanium (IV) content being less than or equal 15% to the total titanium content. It may also contain at least one vanadium compound, an inert solvent, at least one partially polymerized .alpha.-olefin and at least one organometallic activator from groups I to II of the Periodic Classification. Also described is a process for polymerization of olefins in the presence of said catalyst.
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patent: 4163831 (1979-08-01), Gessell
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patent: 4739022 (1988-04-01), Blenkers et al.
patent: 5013701 (1991-05-01), Coosmans et al.
Brusson Jean-Michel
Bujadoux Karel
Mortreux Andre
Petit Francis
Norsolor
Smith Edward J.
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