Process for alkyne hydrosilation using cycloalkenes as catalyst

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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C07F 708

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055655963

ABSTRACT:
An improved process for hydrosilating alkynes with organodihalosilanes and trihalosilanes in the presence of a platinum catalyst selected from a group consisting of platinum halides and reaction product of platinum halides with organosilicon compounds having terminal aliphatic unsaturation. The process uses a cycloalkene comprising about six to 20 carbon atoms as a catalyst modifier to reduce formation of the bis-silated adduct of the alkynes.

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