Process for the preparation of modified block copolymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525256, 525257, 525259, 525261, 525266, 525285, 525301, 525386, C08L 5302

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042924146

ABSTRACT:
A process for preparing a modified block copolymer by graft-reacting at least one maleic acid compound with an aromatic vinyl compound/conjugated diene compound block copolymer containing at least one polymer block mainly composed of a conjugated diene compound and at least one polymer block mainly composed of an aromatic vinyl compound, the aromatic vinyl compound/conjugated diene compound weight ratio being within the range of 5/95 to 97/3, characterized in that said graft-reaction is carried out under conditions wherein the generation of radicals can be substantially inhibited. According to this process, it is possible to prevent gelation of the product in the graft-reaction, and the modified block copolymer obtained has excellent appearance characteristics, mechanical properties, and transparency.

REFERENCES:
patent: 3714295 (1973-01-01), Nakayama
patent: 4033888 (1977-07-01), Kiovsky et al.

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