Production of benzene, toluene, and xylene (BTX) from FCC naphth

Mineral oils: processes and products – Chemical conversion of hydrocarbons – With preliminary treatment of feed

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208 96, 208212, C10G 4500

Patent

active

056859724

ABSTRACT:
Cracked naphtha feeds such as FCC naphtha and coker naphtha are upgraded to produce chemical grade BTX (benzene, toluene, xylene with ethylbenzene) while co-producing a low sulfur gasoline of relatively high octane number. The cracked, sulfur-containing naphtha is processed by hydrodesulfurization followed by treatment over an acidic catalyst, preferably a zeolite such as ZSM-5 or zeolite beta with a hydrogenation component, preferably molybdenum. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product to permit a low sulfur gasoline of blending quality to be obtained with the BTX. The BTX can be extracted from the second stage effluent, preferably from a C.sub.6 -C.sub.8 fraction of this effluent.

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