Preparation of ethenylidenes

Details Preparation of ethenylidenes Preparation of ethenylidenes

1984-08-21

1987-12-15

Rotman, Alan L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

546270, 546350, 549434, 568630, 568648, 570189, 585603, 585605, 585606, 585607, 585435, 585638, C07D491044, C07D31908, C07D21314

Patent

active

047134585

ABSTRACT:
Ketones and aldehydes are converted to ethenylidene-containing compounds by reaction thereof with dimethyl carbonate and a phosphine compound.

REFERENCES:
Fieser and Fieser, Advanced Organic Chemistry, pp. 482-485, Reinhold Pub. Corp., QD 251 F5a C.4, (1961).
Roberts et al., Basic Principles of Organic Chemistry, pp. 1214-1215, Benjamin Pub. QD 251 R58 C.6.
Buehler et al., Survey of Organic Synthesis, pp. 141-143, Wiley-Interscience Pub. QD 262 B7 C.5, (1970), (I).
Buehler et al., Survey of Organic Synthesis, pp. 156-157, Wiley-Interscience Pub. QD 262 B.7 C.3, (1977), (II).

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