Radiation imagery chemistry: process – composition – or product th – Electric or magnetic imagery – e.g. – xerography,... – Radiation-sensitive composition or product
Patent
1990-05-18
1993-01-12
McCamish, Marion E.
Radiation imagery chemistry: process, composition, or product th
Electric or magnetic imagery, e.g., xerography,...
Radiation-sensitive composition or product
G03G 500
Patent
active
051789833
ABSTRACT:
An electrophotographic light-sensitive material comprising a support having thereon a photoconductive layer containing at least inorganic phohtoconductive particles and a binder resin, wherein the binder resin contains (A) at least one resin comprising a graft copolymer having a weight average molecular weight of from 1.0.times.10.sup.3 to 2.0.times.10.sup.4 and containing, as copolymer components, at least (i) a monofunctional macromonomer (M) having a weight average molecular weight of not more than 2.times.10.sup.4 and containing at least one polymer component represented by formula (IIa) or (IIb) shown below and at least one polymer component having at least one polar group selected from the group consisting of --COOH, --PO.sub.3 H.sub.2, --SO.sub.3 H, --OH, and ##STR1## wherein R.sub.1 represents a hydrocarbon group or --OR.sub.2 (wherein R.sub.2 represents a hydrocarbon group), with a polymerizable double bond group represented by formula (I) shown below being bonded to one terminal of the main chain thereof, and (ii) a monomer represented by formula (III) shown below, and (B) at least one resin having a weight average molecular weight of not less than 5.times.10.sup.4, containing at least a recurring unit represented by formula (IV) shown below as a polymer component, and having a crosslinked structure ##STR2## wherein X.sub.0 represents --COO--, --OCO--, --CH.sub.2 OCO--, --CH.sub.2 COO--, --O--, --SO.sub.2, --CO--, --CONHCOO--, --CONHCONH--, --CONHSO.sub.2 --, ##STR3## wherein R.sub.11 represents a hydrogen atom or a hydrocarbon group; a.sub.1 and a.sub.2, which may be the same or different, each represents a hydrogen atom, a halogen atom, a cyano group, a hydrocarbon group, --COO--Z.sub.1, or --COO--Z.sub.1 bonded through a hydrocarbon group (wherein Z.sub.1 represents a substituted or unsubstituted hydrocarbon group) ##STR4## wherein X.sub.1 has the same meaning as X.sub.0 ; Q.sub.1 represents an aliphatic group having from 1 to 18 carbon atoms or an aromatic group having from 6 to 12 carbon atoms; b.sub.1 and b.sub.2, which may be the same or different, each has the same meaning as a.sub.1 and a.sub.2 ; V represents --CN, --CONH.sub.2, or ##STR5## wherein Y represents a hydrogen atom, a halogen atom, a hydrocarbon group, an alkoxyl group, or --COOZ.sub.2, wherein Z.sub.2 represents an alkyl group, an aralkyl group, or an aryl group ##STR6## wherein X.sub.2 has the same meaning as X.sub.0 in formula (I); Q.sub.2 has the same meaning as Q.sub.1 in formula (IIa); and c.sub.1 and c.sub.1, which may be the same or different, have the same meaning as a.sub.1 and a.sub.2 in formula (I) ##STR7## wherein X.sub.3 represents --COO--, --OCO--, --CH.sub.2 OCO--, --CH.sub.2 COO--, --O--, or --SO.sub.2 --; Q.sub.3 represents a hydrocarbon group having from 1 to 22 carbon atoms; and d.sub.1 and d.sub.2, which may be the same or different, each represents a hydrogen atom, a halogen atom, a cyano group, a hydrocarbon group having from 1 to 8 carbon atoms, --COO--Z.sub.3, or --COO--Z.sub.3 bonded through a hydrocarbon group having from 1 to 8 carbon atoms, wherein Z.sub.3 represents a hydrocarbon group having from 1 to 18 carbon atoms.
REFERENCES:
patent: 5009975 (1991-04-01), Kato et al.
patent: 5021311 (1991-06-01), Kato et al.
patent: 5064737 (1991-11-01), Kato et al.
Patent Abstracts of Japan, vol. 13, No. 9, Jan. 11, 1989.
Patent Abstracts of Japan, vol. 13, No. 342, Aug. 2, 1989.
Ishii Kazuo
Kato Eiichi
Crossan S.
Fuji Photo Film Co. , Ltd.
McCamish Marion E.
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