Process for chemical vapor deposition of main group metal nitrid

Coating processes – Coating by vapor – gas – or smoke – Mixture of vapors or gases utilized

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4272551, 4272481, 427314, 4271261, 427255, C23C 1600

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051789116

ABSTRACT:
A process for depositing a thin film of a main group metal nitride, e.g., AlN, GaN or Sn.sub.3 N.sub.4, is provided. The vapors of a main group metal amido compound are mixed with ammonia gas and allowed to react near a substrate heated to a temperature in the range of 100.degree. C. to 400.degree. C. resulting in deposition of a film on the substrate.

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Roy G. Gordon et al., "Silicon Dimethyl Complexes and Ammonia as Precursors for the Atmospheric Pressure Chemical Vapor Deposition of Silicon Nitride Thin Films" Chem. Mat. 2(5), 480 (Sep.-Oct., 1990).
Roy G. Gordon et al., "Atmospheric Pressure Chemical Vapor Deposition of Gallium Nitride Thin Films" Mat. Res. Soc. Symp. vol. 204, Materials Research Society, Pittsburgh, Pa.; pp. 95-99 (1991).
Roy G. Gordon et al., "Atmospheric Pressure Chemical Vapor Deposition of Aluminum Nitride Thin Films at 200.degree.-250.degree. C." J. Mater. Res. 6(1), 5-7 (Jan, 1991).
Anonymous "Ammonolysis of Tetrakisdimethylaminosilane for Low Pressure Chemical Vapor Deposition of Silicon Nitride" Res. Disclosure 314, 494 (Jun., 1990).

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