Preparation of hydroxyalkyl phosphine oxides and sulfides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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204158R, C07F 953, B01J 110

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040072290

ABSTRACT:
A process for the preparation of 2-hydroxyalkylphosphine oxides and sulfides. The corresponding 2-acyloxyphosphine is hydrolyzed (or alcoholyzed) and oxidized, in either order, to produce the desired 2-hydroxyalkylphosphine oxide or sulfide. The product may contain one, two or three 2-hydroxyalkyl groups, depending on the phosphine starting material used.

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Hellmann et al., Ann. V659, pp. 49-63 (1962).
Arbuzov et al., Izv. Akad. Nauk SSSR, Otd. Khim. Nauk., (3) pp. 502-506 (1963). Izv. Akad. Nauk. SSSR, Otd. Khim. Nauk., (3) pp. 502-506 (1963).
Arbuzov et al., Nekotorye Voprosy Organicheskoy Khinii, pp. 244-255 (1964).
Arbuzov et al., Iz. Akad. Nauk. SSSR, Ser. Khim, 290 (1962).

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