Purified catalyst support

Details Purified catalyst support Purified catalyst support

1981-09-10

1983-05-03

Garvin, Patrick

Compositions

Preservative agents

Anti-oxidants or chemical change inhibitants

252441, 526125, 423498, C08F 464, C08F 402

Patent

active

043820190

ABSTRACT:
This invention relates to pretreating the support material for a polymerization catalyst comprising magnesium chloride with an active hydrogen compound such as an organic acid phosphate or a phenol in order to transform substantially elemental magnesium and other impurities. The impure magnesium chloride originates as a by-product from the manufacture of magnesium alkyls by the reaction of alkyl chlorides with elemental magnesium. Succeeding steps are activating the support material with an electron donor and treating the activated product with a titanium halide.
The invention also includes the novel catalytic component containing titanium halide, itself, the process for making that component, use of this catalytic system for polymerizing olefins such as propylene, and the purification step for magnesium chloride, itself.

REFERENCES:
patent: 3412174 (1968-11-01), Kroll
patent: 4085276 (1978-04-01), Toyota et al.
patent: 4149990 (1979-04-01), Giannini et al.
patent: 4186107 (1980-01-01), Wagner
patent: 4243552 (1981-01-01), Welch et al.
patent: 4312782 (1982-01-01), Mink et al.

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