Preparation of vinyl ether terminated polyesters

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528274, 528300, 528301, 528308, 528392, 525438, 525445, 525447, 560 91, 560198, C08G 6347

Patent

active

052868354

ABSTRACT:
Vinyl ether terminated ester oligomers having a range of molecular weights are prepared by reacting a vinyl ether terminated polybasic ester with a polyol in the presence of a catalyst. Continual removal of a hydroxy monovinyl ether avoids formation compounds containing acetal moieties. Alternatively, a polybasic ester is chain extended with a polyol with continual removal of the alcohol by-product. Then, the terminal ester moieties are end capped with a monohydroxy vinyl ether. The oligomers have application in coatings and the like.

REFERENCES:
patent: 4749807 (1988-06-01), Lapin et al.
patent: 4775732 (1988-10-01), Lapin
patent: 4845265 (1989-07-01), Lapin

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