Process for preparing nitriles

Organic compounds -- part of the class 532-570 series – Organic compounds – Nitrogen attached directly or indirectly to the purine ring...

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546286, 546287, C07D24124, C07D21357

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active

047788909

ABSTRACT:
A heteroaromatic nitrile is prepared in a high selectivity and yield by catalytically reacting an alkyl-substituted heteroaromatic compound with molecular oxygen and ammonia in a molar ratio of oxygen to ammonia of not larger than 1.6:1 in a gaseous phase in the presence of a catalyst comprising a vanadium-phosphorus oxide of the formula:

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patent: 4603207 (1986-07-01), DiCosimo et al.
Forni, Applied Catalysis, 20 (1986), pp. 219-230.

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