Method for polymerizing ethylenically unsaturated monomer with n

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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5263297, C08F 432

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active

045229910

ABSTRACT:
Organic peroxydicarbonates represented by the following graphic formula are described. ##STR1## In the formula, R and R' are each selected from an alkyl group containing from 1 to 4 carbon atoms, a cycloalkyl group of from 5 to 7 carbon atoms, a C.sub.1 -C.sub.4 alkyl substituted cycloalkyl group, or participate in a cycloalkyl group having from 5 to 7 carbon atoms, provided that when one of R and R' is cycloalkyl, the other is alkyl. The peroxydicarbonates are useful as initiators for the polymerization or copolymerization of ethylenically unsaturated monomers or the cross-linking of unsaturated polyester resins. The organic peroxydicarbonates can be used in combination with commercially available peroxydicarbonates, particularly those having a shorter half-life.

REFERENCES:
Chem. Abstracts vol. 82, 1975 entry 44078d.

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