Complexes of metal salts of hydroxybenzoic acids and piperidines

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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260 458N, 260 4575N, 544 64, 544129, 544130, 546187, 546188, 546189, 546190, 546191, 546207, 546208, 546214, 546221, 546222, 546223, 546224, 546226, 546227, 546238, 546239, C07F 1504, C07F 1506, C07F 306

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042476941

ABSTRACT:
The invention relates to metal salts of hydroxybenzoic acids which are complexed with a 4-amino-polyalkylpiperidine derivative or to mixed metal salts of a hydroxybenzoic acid and a polyalkylpiperidine carboxylic acid which may be complexed or not with an 4-amino-polyalkylpiperidine. The metal cation may be that of a di- or trivalent metal such as Ni, Co, Al, Zn or Ca. From hydroxybenzoic acids the 3,5-di-tert.butylbenzoic acid is preferred.
These salts are valuable light stabilizers for plastics, especially for polyolefins, styrene polymers and polyamides or polyurethanes respectively. The salts show a strong tendency to retain water. For high compatibility with plastics a low water content is of importance.

REFERENCES:
patent: 3189630 (1965-06-01), Smutny
patent: 3684765 (1972-08-01), Matsui et al.
patent: 3901931 (1975-08-01), Rasberger et al.
patent: 3904581 (1975-09-01), Murayama
patent: 3939168 (1976-02-01), Cook
patent: 3948852 (1976-04-01), Rasberger et al.
patent: 4033928 (1977-07-01), Randell et al.
patent: 4186267 (1980-01-01), Rasberger

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