Tough soluble aromatic thermoplastic copolyimides

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528125, 528128, 528172, 528173, 528176, 528179, 528183, 528188, 528220, 528229, 528350, C08G 7310

Patent

active

060489596

ABSTRACT:
Tough, soluble, aromatic, thermoplastic copolyimides were prepared by reacting 4,4'-oxydiphthalic anhydride, 3,4,3',4'-biphenyltetracarboxylic dianhydride and 3,4'-oxydianiline. Alternatively, these copolyimides may be prepared by reacting 4,4'-oxydiphthalic anhydride with 3,4,3',4'-biphenyltetracarboxylic dianhydride and 3,4'-oxydiisocyanate. Also, the copolyimide may be prepared by reacting the corresponding tetra acid and ester precursors of 4,4'-oxydiphthalic anhydride and 3,4,3',4'-biphenyltetracarboxylic dianhydride with 3,4'-oxydianiline. These copolyimides were found to be soluble in common amide solvents such as N,N'-dimethyl acetamide, N-methylpyrrolidinone, and dimethylformamide allowing them to be applied as the fully imidized copolymer and to be used to prepare a wide range of articles.

REFERENCES:
patent: 5147966 (1992-09-01), St. Clair et al.
patent: 5171828 (1992-12-01), Meterko et al.
patent: 5502157 (1996-03-01), Chang et al.
patent: 5639850 (1997-06-01), Bryant
patent: 5741883 (1998-04-01), Bryant
patent: 5840828 (1998-11-01), St. Clair et al.

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