Hydrocarbon oxidations catalyzed by iron coordination complexes

Details Hydrocarbon oxidations catalyzed by iron coordination complexes Hydrocarbon oxidations catalyzed by iron coordination complexes

1987-06-26

1990-02-13

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

260413, 2604109R, 560241, 568398, 568910, 5689105, 562512, 562549, C07C 4532, C07C 4533

Patent

active

049008714

ABSTRACT:
Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O.sub.2 to form such products as alcohols, ketones, and the like selectively high yields when there is employed as the catalyst a coordination complex containing an iron center and a halogenated ligand having the structure ##STR1## where Fe is iron; " .circle. " is a ligand; X is a halogen substituent of the ligand; and A is an anion.

REFERENCES:
patent: 3816548 (1974-06-01), Williams et al.
patent: 3873625 (1975-03-01), Barone
patent: 4028423 (1977-06-01), Brownstein
patent: 4459427 (1984-07-01), Middleton et al.

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